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Types of Alloy Steels

In ANSI and SAE, the alloy types are classed by the use of a four-digit numbering system. The first digit indicates the type of alloy steel, the second digit is an approximation of the major alloy percent, and the last two digits represent the carbon content of an alloy. As an example, AISI 2320 represents nickel (2xxx), in the amount of 3.5 % (x3xx), with a carbon content of 0.20% (xx20).

The table below provides a summary of selected types of alloy steels and their characteristics. High alloy steels, such as stainless steels and tool steels, are discussed separately.

Type ANSI Number Description Application
Mn Steels (13xx) Mn is one of the least costly alloying elements to aids in fine grain structur. Its effects in steels depends upon the C content of the steel. When C is unavailable, Mn dissolves in the gamma or alpha iron matrix, adding considerable strength. A high Mn content changes the steel from pearlite to martensite, with some increase in hardness and brittleness. An alloy containing about 12% Mn is called Hadfield steel. With the proper heat treatment, this alloy develops high strength, good ductility and resistance to wear. Primarily for making axles, forgings, gears, shafts, and gun barrels. Hadfield steel is used extensively for crushing, grinding and powershovel machinery, and for railroad tracks.
Ni Steels 2xxx Ni is one of the oldest and most common of alloy elements. It has high solubility in gamma iron, and is soluble in ferrite. It aids in corrosion resistance, impact strength and toughness, and slows down grain growth at high temperatures. Small amounts of nickel (1.5-3.0%) are used for high-strength structural steel castings and forgings. The 3.5% nickel, low carbon alloys are used for such products as carburized connecting rods, gears, and kingpins. The 5% nickel alloys are used in heavy equipment, truck cams, crankshafts, and other heavy-duty products.
Ni-Cr Steels 3xxx The Ni increases ductility and toughness while the Cr aids hardenability and wear resistance. Low Ni-Cr alloys, usually in a ratio of 2.5 to 1, add the combined properties of each element with greater effect than when each is added separately. Carburized low carbon parts such as cams, connecting rods, drive shafts, gears, and piston pins.
Mo Steels 4xxx Mo is a costly alloy element having limited solubility in alpha and gamma iron. It has high chemical affinity for carbon and, therefore, increases alloy hardness. Molybdenum is often used in combination with Cr and/or Ni to make carburized structural parts for aircraft.
Low Cr Steels 5xxx Cr is an inexpensive carbide-forming alloy having fair solubility in gamma iron and limited solubility in ferrite. Low C-Cr alloys are usually carburized and case hardened to provide combined wear resistance and toughness. Medium C-Cr alloys are commonly used in axles, bolts, springs, and studs for automobiles. They are also used in tool steel for chisels, dies, drills, files, knives, and shears.
Cr-V Steels 6xxx Cr-V alloys are noted for fine-grain size, excellent hardenability, high strength, and toughness. V is one of the most expensive alloys, yet it is one of the most important in terms of grain growth and carbide formation. Cr-V steels are widely used in heavy forgings, axles, springs, and tools, depending upon their carbon content. Low C alloys are case hardened, as necessary.
Ni-Cr-Mo Steels 8xxx and 9xxx Meet critical needs for hardness, strength, and corrosion resistance. Special emphasis has been placed upon end-quench hardness tests for these alloys. With this added hardenability data, these alloys are identified and sold with the letter H, as follows: 4140H, 5140H, 8640H, as well as others. Ni-Cr-Mo alloys are used in their carburized state for heavy equipment and aircraft parts.

 

 
 
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